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Abstract G10.21-0.31 is a 70 μ m dark high-mass starless core ( M > 300 M ⊙ within r < 0.15 pc) identified in the Spitzer, Herschel, and APEX continuum surveys, and is believed to harbor the initial stages of high-mass star formation. We present Atacama Large Millimeter/submillimeter Array (ALMA) and Submillimeter Array observations to resolve the internal structure of this promising high-mass starless core. Sensitive high-resolution ALMA 1.3 mm dust continuum emission reveals three cores of mass ranging within 11–18 M ⊙ , characterized by a turbulent fragmentation. Cores 1, 2, and 3 represent a coherent evolution of three different stages, characterized by outflows (CO and SiO), gas temperature (H 2 CO), and deuteration (N 2 D + /N 2 H + ). We confirm the potential for formation of high-mass stars in G10.21 and explore the evolution path of high-mass star formation. Yet, no high-mass prestellar core is present in G10.21. This suggests a dynamical star formation where cores grow in mass over time.